QAChemicalTestsOnOrganicCompounds

Chemical Tests to Infer and Identify the Functional Groups and type of Organic Compounds

Study the Tests and accompanying Observations on performing the chemical tests to the Inferred Organic ompounds and functional groups present
TEST: When solution warmed with acidified potassium dichromate (VI) solution ; OBSERVATION: it turned from orange to greenPossibly a primary, secondary alcohol or aldehyde
TEST: When shaken with bromine solution; OBSERVATION: yellow solution decolourisedPresence of alkene
TEST: When shaken with bromine solution; OBSERVATION: yellow solution decolourised and white ppt also formedPresence of phenol
TEST: Warmed with aqueous NaOH, acidify with dil HNO3 then add aq AgNO3; OBSERVATION: white, cream or yellow pptPresence of one of the haloalkanes; C-Cl, C-Br, C-I
TEST: Add Phosphorus Pentachloride; OBSERVATIONS: Effervescence with steamy fumes of HClPresence of OH group in alcohols and carboxylic acids
TEST: 2-4-dinitrophenylhydrazine; OBSERVATION: orange pptPresence of carbonyl group, C=O in aldehydes and ketones
TEST: Boil with Fehlings Solution; OBSERVATION: Blue solution gives red pptPresence of aldehyde
TEST: Warm with ammoniacal silver nitrate solution; OBSERVATION: Silver mirror produced at bottom of test tubePresence of aldehyde
TEST: Add sodium or potassium hydrogencarbonate to sample; OBSERVATION: Effervescence with CO2 evolvedPresence of carboxylic acids
TEST: Iodoform test; add iodine in alkaline solution to sample or aqueous potassium iodide and sodium(I) chlorate; OBSERVATION: pale yellow pptPresence of methyl group attached to the carbon atom in the carbonyl group; could be methyl ketone or ethanal, methyl secondary alcohol or ethanol
TEST: Warm with carboxylic acid and a few drops of conc sulphuric acid; OBSERVATION: Ester smell or glue likePresence of alcohol
TEST: Add sodium nitrite and dil HCl followed by an alkaline solution of phenol in ice-cold conditions; OBSERVATION: Orange pptPresence of aromatic amine